Veröffentlichungen 2023
2022
M. L. Weber, G. Lole, A. Kormanyos, A. Schwiers, L. Heymann, F. D. Speck, T. Meyer, R. Dittmann, S. Cherevko, C. Jooss, C. Baeumer, and F.Gunkel, Atomistic Insights into Activation and Degradation of La0.6Sr0.4CoO3−δ Electro- catalysts under Oxygen Evolution Conditions , J. Am. Chem. Soc. 2022, 144, 39, 17966–17979, (DOI: 10.1021/jacs.2c07226).
L. Heymann, M. L Weber, M. Wohlgemuth, M. Risch, R. Dittmann, C. Baeumer, Felix Gunkel, Separating the Effects of Band Bending and Covalency in Hybrid Perovskite Oxide Electrocatalyst Bilayers for Water Electrolysis ,ACS Appl. Mater. Interfaces 2022, 14, 12, 14129–14136, (DOI: 10.1021/acsami.1c20337).
M. Wohlgemuth, M. L Weber, L. Heymann, C. Baeumer*, F. Gunkel, Activity-Stability Relationships in Oxide Electrocatalysts for Water Electrolysis , Front. Chem.2022, 10, 913419, (DOI: 10.3389/fchem.2022.913419).
J. Geppert, P. Röse, S.Czioska, D. Escalera-López, A. Boubnov, E. Saraçi, S. Cherevko, J.-D. Grunwaldt, and U. Krewer, Microkinetic Analysis of the Oxygen Evolution Performance at Different Stages of Iridium Oxide Degradation , J. Am. Chem. Soc. 2022, 144, 29, 13205–13217, (DOI: doi.org/10.1021/jacs.2c03561).
J. Geppert, P. Röse, S.Czioska, D. Escalera-López, A. Boubnov, E. Saraçi, S. Cherevko, J.-D. Grunwaldt, and U. Krewer, Microkinetic Analysis of the Oxygen Evolution Performance at Different Stages of Iridium Oxide Degradation , J. Am. Chem. Soc. 2022, 144, 29, 13205–13217, (DOI: doi.org/10.1021/jacs.2c03561).
G. G. Behrendt, N. Prinz, A. Wolf, L. Baumgarten, A. Gaur, J.-D. Grunwaldt, M. Zobel, M. Behrens, S. Mangelsen, Substitution of Copper by Magnesium in Malachite: Insights into the Synthesis and Structural Effects, Inorg. Chem. 2022, (DOI: doi.org/10.1021/acs.inorgchem.2c01976)
S. Czioska, K. Ehelebe, J. Geppert, D. Escalera-López, A. Boubnov, E. Saraçi, B. Mayerhöfer, U. Krewer, S. Cherevko, J.-D. Grunwaldt, Heating up the OER: Investigation of IrO2 OER Catalysts as Function of Potential and Temperature , ChemElectroChem 2022, 9, e20220051, (DOI: doi.org/10.1002/celc.202200514)
J. Pazdera, Jakub, D. Issayeva, J. Titus, Juliane, R. Glaser, O. Deutschmann, A. Jentys, Impact of the Local Environment of Amines on the Activity for CO2 Hydrogenation over Bifunctional Basic - Metallic Catalysts , ChemCatChem 2022, 14, e2022006, (DOI: 10.1002/cctc.202200620)
S. Das, R. Pashminehazar, S. Sharma, S. Weber, T. Sheppard, New Dimensions in Catalysis Research with Hard X-Ray Tomography , Chemie Ingenieur Technik 2022, 94. 1591-1610, (DOI: 10.1002/cite.202200082)
D. Weber, K. M. Wadlinger, M. M. Heinlein, T. Franken, Modifying Spinel Precursors for Highly Active and Stable Ni-based CO2 Methanation Catalysts , ChemCatChem 2022, e202200563, (DOI: 10.1002/cctc.202200620)
K. L. Abel, T. Beger, D. Poppitz, R. T. Zimmermann, O. Kuschel, K. Sundmacher, R. Glaeser, Monolithic Al2O3 Xerogels with Hierarchical Meso-/Macropore System as Catalyst Supports for Methanation of CO2 , ChemCatChem 2022, 14, e202200288 (DOI: 10.1002/cctc.202200288)
S. Schlicher, N. Prinz, J. Buerger, A. Omlor, C. Singer, M. Zobel, R. Schoch, J. K. N. Lindner, V. Schuenemann, S. Kureti, M. Bauer, Quality or Quantity? How Structural Parameters Affect Catalytic Activity of Iron Oxides for CO Oxidation , Catalysts 2022, 12, 675. (DOI: 10.3390/catal12060675)
K.L. Abel, S. Weber, D. Poppitz, J. Titus, T. L. Sheppard, R. Glaeser, Thermally stable mesoporous tetragonal zirconia through surfactant-controlled synthesis and Si-stabilization , RSC Advances 2022, 12, 16875-16885, (DOI: 10.1039/d2ra01459a)
A. Arinchtein, M. Y. Ye, Q. X. Yang, C. Kreyenschulte, A. Wagner, M. Frisch, A. Brueckner, E. Kondratenko, R. Kraehnert, Dynamics of Reaction-Induced Changes of Model-Type Iron Oxide Phases in the CO2-Fischer-Tropsch-Synthesis , ChemCatChem 2022, 14, e202200240, (DOI: 10.1002/cctc.202200240)
R. Sachse, M. Moor, R. Kraehnert, V. D. Hodoroaba, A. Hertwig, Ellipsometry-Based Approach for the Characterization of Mesoporous Thin Films for H-2 Technologies , Advanced Engineering Materials 2022, 24, 2101320, (DOI: 10.1002/adem.202101320)
S. Weber, R. T. Zimmermann, J. Bremer, K.L. Abel, D. Poppitz, N. Prinz, J. Ilsemann, S. Wendholt, Q. X. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X. H. Huang, C. Kuebel, E. Kondratenko, M. Bauer, M. Baeumer, M. Zobel, R. Glaeser, K. Sundmacher, T. L. Sheppard, Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation , ChemCatChem 2022, 14, e202101878, (DOI: 10.1002/cctc.202101878)
S. Weber, A. Diaz, M. Holler, A. Schropp, M. Lyubomirskiy, K. L. Abel, M. Kahnt, A. Jeromin, S. Kulkarni, T. F. Keller, R. Glaser, Roger T. L. Sheppard, Evolution of Hierarchically Porous Nickel Alumina Catalysts Studied by X-Ray Ptychography , Advanced Science 2022, 9, 2105432, (DOI: 10.1002/advs.202105432)
F. Hess, S. Rohrlack, M. Knapp, H. Over, Evidence of a Tetrahedrally Coordinated RuO4 Surface Complex on RuO2(100) : Density Functional Theory and Beyond, Journal of Physical Chemistry C 2022, 126, 946-956, (DOI: 10.1021/acs.jpcc.1c08787)
R. Amirbeigiarab, J. Tian, A. Bagger, Jan Rossmeisl, O. Magnussen: Structure of the (bi)carbonate adlayer on Cu(100) electrodes . Angew. Chem. Int. Ed. 2022, e202211360 (DOI: 10.1002/anie.202211360).
G. Behrendt, B. Mockenhaupt, N. Prinz, M. Zobel, E.J. Ras and M. Behrens: CO Hydrogenation to Methanol over Cu/MgO Catalysts and Their Synthesis from Amorphous Magnesian Georgeite Precursors , ChemCatChem2022,14, e20220029 (2022) (DOI: 10.1002/cctc.202200299).
M. Rüscher, A. Herzog, J. Timoshenko, H. Jeon, W. Frandsen, S. Kühl and B. Roldan Cuenya: Tracking heterogeneous structural motifs and the redox behaviour of copper-zinc nanocatalysts for the electrocatalytic CO2 reduction using operando time resolved spectroscopy and machine learning , Catalysis Science & Technology 12 (9), 3028–3043 (2022). (DOI: 10.1039/D2CY00227B).
J. Timoshenko, A. Bergmann, C. Rettenmaier, A. Herzog, R. M. Arán-Ais, H. S. Jeon, F. T. Haase, U. Hejral, P. Grosse, S. Kühl, E. M. Davis, J.Tian, O. Magnussen, B. R. Cuenya, Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses . Nat Catal 5, 259–267 (2022). (DOI: 10.1038/s41929-022-00760-z).
N. Daems, D. Choukroun, P. Merino, C. Rettenmaier, L. Pacquets, A. Bergmann, G. Santoro, L. Vázquez, L. Martínez, B. Roldan Cuenya, J. A. M. Gago, T. Breugelmans, Steering Hydrocarbon Selectivity in CO2 Electroreduction over Soft-Landed CuOx Nanoparticle-Functionalized Gas Diffusion Electrodes , ACS Appl. Mater. Interfaces 2022, 14, 2691−2702 (DOI:10.1021/acsami.1c17998).
S. Weber, A. Diaz, M. Holler, A. Schropp, M. Lyubomirskiy, K. L. Abel, M. Kahnt, A. Jeromin, S. Kulkarni, T. F. Keller, R. Gläser, T. L. Sheppard, Evolution of Hierarchically Porous Nickel Alumina Catalysts Studied by X-Ray Ptychography , Advanced Science 9,8 (2022) (DOI: 10.1002/advs.202105432).
S. Weber, R.T. Zimmermann, J. Bremer, K. L. Abel, D. Poppitz, N. Prinz, J. Ilsemann, S.Wendholt, Q. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X.Huang, C. Kübel, E. Kondratenko, M. Bauer, M. Bäumer, M. Zobel, R. Gläser, K. Sundmacher, T.L. Sheppard, Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation , ChemCatChem (2022) (DOI:10.1002/cctc.202101878).
D. Nikolić, C. Seidel, M. Felischak, T. Miličić, A. Kienle, A. Seidel-Morgenstern, M. Petkovska, Forced periodic operations of a chemical reactor for methanol synthesis – the search for the best scenario based on Nonlinear Frequency Response Method. Part I Single input modulations , Chemical Engineering Science 248 (2022) 117134 (DOI: 10.1016/j.ces.2021.117134).
D. Nikolić, C. Seidel, M. Felischak, T. Miličić, A. Kienle, A. Seidel-Morgenstern, M. Petkovska, Forced periodic operations of a chemical reactor for methanol synthesis - the search for the best scenario based on Nonlinear Frequency Response Method. Part II Simultaneous modulation of two inputs , Chemical Engineering Science 248 (2022) 117133 (DOI: 10.1016/j.ces.2021.117133).
R. T. Zimmermann, J. Bremer, K. Sundmacher, Load-flexible fixed-bed reactors by multi-period design optimization , Chem. Eng. J. 428 (2022) 130771 (DOI: 10.1016/j.cej.2021.130771).
2021
P. Grosse, A. Yoon, C. Rettenmaier, A. Herzog, S.W. Chee and B. Roldan Cuenya: Dynamic transformation of cubic copper catalysts during CO2 electroreduction and its impact on catalytic selectivity . Nature Communications 12, 6736 (2021) (DOI: 10.1038/s41467-021-26743-5).
L. Pandit, M.A. Serrer, E. Saraci, A. Boubnov, J.-D. Grunwaldt, Versatile in situ/operando Setup for Studying Catalysts by X-Ray Absorption Spectroscopy under Demanding and Dynamic Reaction Conditions for Energy Storage and Conversion , Chemistry-Methods (2021) accepted (DOI: 10.1002/cmtd.202100078).
H. Ridder, C. Sinn, G. R. Pesch, W. Dreher, J. Thöming, Spatially resolved direct gas-phase thermometry in chemical reactors using NMR , Chemical Engineering Journal (2021) 133583 (DOI: 10.1016/j.cej.2021.133583).
J. Weiß, C. Rautenberg, T. Rall, C. Kubis, E. Kondratenko, U. Bentrup, A. Brückner, A Versatile Ambient-to-High-Pressure Reaction Transmission Cell for in situ/operando Infrared Spectroscopic Investigations , Chemistry-Methods 1/7 (2021) 308-314 (DOI: 10.1002/cmtd.202100024).
J. Pazdera, E. Berger, J. A. Lercher, A. Jentys, Conversion of CO2 to methanol over bifunctional basic-metallic catalysts , Catalysis Communications 159 (2021) 106347 (DOI: 10.1016/j.catcom.2021.106347).
S. Weber, D. Batey, S. Cipiccia, M. Stehle, K. L. Abel, R. Gläser, T. L. Sheppard, Hard X-ray Nanotomography for 3D Analysis of Coking in Nickel-based Catalysts , Angew. Chem. Int. Ed. 60/40 (2021) 21772-21777 (DOI: 10.1002/anie.202106380).
A. Arinchtein, M.-Y. Ye, M. Geske, M. Frisch, R. Kraehnert, Influence of Phase Composition and Pretreatment on the Conversion of Iron Oxides into Iron Carbides in Syngas Atmospheres , Catalysts 11/7 (2021) 773 (DOI: 10.3390/catal11070773).
L. Pandit, A. Boubnov, G. Behrendt, B. Mockenhaupt, C. Chowdhury, J. Jelic, A.-L. Hansen, E. Saraçi, E.-J. Ras, M. Behrens, F. Studt, J.-D. Grunwaldt, Unravelling the Zn-Cu Interaction during Activation of a Zn-promoted Cu/MgO Model Methanol Catalyst , ChemCatChem 13/19 (2021) 4120-4132 (DOI: 10.1002/cctc.202100692).
S. Czioska, A. Boubnov, D. Escalera-Lopez, J. Geppert, A. Zagalskaya, P. Röse, E. Saraçi, V. Alexandrov, U. Krewer, S. Cherevko, J.-D. Grunwaldt, Increased Ir-Ir Interaction in Iridium Oxide during the Oxygen Evolution Reaction at High Potentials Probed by Operando Spectroscopy , ACS Catalysis 11 (2021) 10043–10057 (DOI: 10.1021/acscatal.1c02074).
C. Seidel, D. Nikolic, M. Felischak, M. Petkovska, A. Seidel-Morgenstern, A. Kienle, Optimization of methanol synthesis under forced periodic operation , Processes 9/5 (2021) 872 (DOI: 10.3390/pr9050872).
A. S. Skrypnik, Q. Yang, A. A. Matvienko, V. Yu. Bychkov, Yu. P. Tulenin, H. Lund, S. A. Petrov, R. Kraehnert, A. Arinchtein, J. Weiss, A. Brueckner, E. V. Kondratenko, Understanding reaction-induced restructuring of well-defined FexOyCz compositions and its effect on CO2 hydrogenation , Applied Catalysis B: Environmental 291 (2021) 120121 (DOI: 10.1016/j.apcatb.2021.120121).
J. Becher, S. Weber, D. Ferreira Sanchez, D. E. Doronkin, J. Garrevoet, G. Falkenberg, D. Motta Meira, S. Pascarelli, J.-D. Grunwaldt, T. L. Sheppard, Sample Environment for Operando Hard X-ray Tomography — An Enabling Technology for Multimodal Characterization in Heterogeneous Catalysis , Catalysts 11 (2021) 459 (1-18) (DOI: 10.3390/catal11040459).
C. Sinn, J. Wentrup, G. R. Pesch, J. Thöming, Heat Transport in Open-Cell Foams: CFD Analysis of Artificial Heat Sources vs Fully Resolved Exothermal Reactions , Ind. Eng. Chem. Res. 60/12 (2021) 4542-4551 (DOI: 10.1021/acs.iecr.0c05982).
D. Escalera López, S. Czioska, J. Geppert, A. Boubnov, P. Röse, E. Saraҫi, U. Krewer, J.-D. Grunwaldt, S. Cherevko, Phase and surface composition-dependent electrochemical stability of Ir-Ru nanoparticles during oxygen evolution reaction , ACS Catalysis 11 (2021) 9300-9316 (DOI: 10.1021/acscatal.1c01682).
M.-A. Serrer, M. Stehle, M. L. Schulte, H. Besser, W. Pfleging, E. Saraçi, J.-D. Grunwaldt, Spatially-Resolved Insights Into Local Activity and Structure of Ni-based CO2 Methanation Catalysts in Fixed-bed Reactors , ChemCatChem (2021) (DOI: 10.1002/cctc.202100490).
C. Zhan, F. Dattila, C. Rettenmaier, A. Bergmann, S. Kühl, R. García-Muelas, N. López, B. Roldan Cuenya, Revealing the CO Coverage Driven C-C Coupling Mechanism for Electrochemical CO2 Reduction on Cu2O Nanocubes via Operando Raman Spectroscopy , ACS Catalysis (2021) accepted (DOI: 10.1021/acscatal.1c01478).
M. Lopez Luna, J. Timoshenko, D. Kordus, C. Rettenmaier, S. W. Chee, A. Hoffman, S. R. Bare, S. Shaikhutdinov, B. Roldan Cuenya, Role of the Oxide Support on the Structural and Chemical Evolution of Fe Catalysts during the Hydrogenation of CO2 , ACS Catalysis 11 (2021) 6175 (DOI: 10.1021/acscatal.1c01549).
J. Stahl, J. Ilsemann, S. Pokhrel, M. Schowalter, C. Tessarek, A. Rosenauer, M. Eickhoff, M. Bäumer, L. Mädler, Comparing Co-catalytic Effects of ZrOx, SmOx, and Pt on COx Methanation over Co-based Catalysts Prepared by Double Flame Spray Pyrolysis , ChemCatChem (2021) (DOI: 10.1002/cctc.202001998).
H. Ridder, C. Sinn, G. R. Pesch, J. Ilsemann, W. Dreher, J. Thöming, A large fixed bed reactor for MRI operando experiments at elevated temperature and pressure , Review of Scientific Instruments 92 (2021) 043711 (DOI: 10.1063/5.0044795).
H. S. Jeon, J. Timoshenko, C. Rettenmaier, A. Herzog, A. Yoon, S. W. Chee, S. Oener, U. Hejral, F. T. Haase, B. Roldan Cuenya, Selectivity control of Cu nanocrystals in a gas-fed flow cell through CO2 pulsed electroreduction , J. Am. Chem. Soc. 143/19 (2021) 7578-7587 (DOI: 10.1021/jacs.1c03443).
J. Geppert, F. Kubannek, P. Röse, U. Krewer, Identifying the Oxygen Evolution Mechanism by Microkinetic Modelling of Cyclic Voltammograms , Electrochimica Acta (2021) (DOI: 10.1016/j.electacta.2021.137902).
K. L. Fischer, H. Freund, Intensification of Load Flexible Fixed Bed Reactors by Optimal Design of Staged Reactor Setups , Chemical Engineering and Processing - Process Intensification 159 (2021) 108183 (DOI: 10.1016/j.cep.2020.108183).
M. Felischak, L. Kaps, C. Hamel, D. Nikolic, M. Petkovska, A. Seidel-Morgenstern, Analysis and experimental demonstration of forced periodic operation of an adiabatic stirred tank reactor: Simultaneous modulation of inlet concentration and total flow-rate , Chemical Engineering Journal 410 (2021) 128197 (DOI: 10.1016/j.cej.2020.128197).
A. Herzog, A. Bergmann, H. Sang Jeon, J. Timoshenko, S. Kühl, C. Rettenmaier, M. Lopez Luna, F. T. Haase, B. Roldán Cuenya, Operando Investigation of Ag‐decorated Cu2O Nanocube Catalysts with enhanced CO2 Electroreduction toward Liquid Products , Angew. Chem. Int. Ed. 60/13 (2021) 7426-7435 (DOI: 10.1002/anie.202017070).
S. W. Chee, T. Lunkenbein, R. Schlögl, B. Roldan Cuenya, In situ and Operando Electron Microscopy in Heterogeneous Catalysis – Insights into Multi-Scale Chemical Dynamics , J. Phys. Condens. Matter 33 (2021) 153001 (DOI: 10.1088/1361-648X/abddfd).
J. Timoshenko, B. Roldan Cuenya, In situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy , Chem. Rev. 121 (2021) 882 (DOI: 10.1021/acs.chemrev.0c00396).
G. H. Simon, C. S. Kley, B. Roldan Cuenya, Potential-dependent Morphology of Copper Catalysts During CO2 Electroreduction Revealed by In Situ Atomic Force Microscopy , Angew. Chem. Int. Ed. 60 (2021) 2561 (DOI: 10.1002/anie.202010449).
C. Sinn, J. Wentrup, G. R. Pescha, J. Thöming, L. Kiewidt, Structure-heat transport analysis of periodic open-cell foams to be used as catalyst carriers , Chemical Engineering Research and Design 166 (2021) 209-219 (DOI: 10.1016/j.cherd.2020.12.007).
2020
C. Seidel, A. Kienle, Methanol kinetics from optimal dynamic experiments , Computer Aided Chem. Eng. 84 (2020) 745-750 (DOI: 10.1016/B978-0-12-823377-1.50002-1).
M.-A. Serrer, A. Gaur, J. Jelic, S. Weber, C. Fritsch, A. H. Clark, E. Saraçi, F. Studt, J.-D. Grunwaldt, Structural dynamics in Ni–Fe catalysts during CO2 methanation – role of iron oxide clusters , Catal. Sci. Technol. 10 (2020) 7542 (DOI: 10.1039/d0cy01396j).
J. Bitzer, A. Titze-Alonso, A. Roshdy, W. Kleist, The introduction of functional side groups and the application of the mixed-linker concept in divalent MIL-53(Ni) materials , Dalton Trans. 49 (2020) 9148-9154 (DOI: 10.1039/D0DT01222J).
C. Sinn, F. Kranz, J. Wentrup, J. Thöming, G. D. Wehinger, G. R. Pesch, CFD Simulations of Radiative Heat Transport in Open-Cell Foam Catalytic Reactors , Catalysts 10(6) (2020) 716 (DOI: 10.3390/catal10060716).
C. Sinn, J. Wentrup, J. Thöming, G. R. Pesch, Influence of Pressure, Velocity and Fluid Material on Heat Transport in Structured Open-Cell Foam Reactors Investigated Using CFD Simulations , ChemEngineering 4(4) (2020) 61 (DOI: 10.3390/chemengineering4040061).
S. Weber, K. L. Abel, R. T. Zimmermann, X. Huang, J. Bremer, L. K. Rihko-Struckmann, D. Batey, S. Cipiccia, J. Titus, D. Poppitz, C. Kübel, K. Sundmacher, R. Gläser, T. L. Sheppard, Porosity and Structure of Hierarchically Porous Ni/Al2O3 Catalysts for CO2 Methanation , Catalysts 10(12) (2020) 1471 (DOI: 10.3390/catal10121471).
T. Weber, V. Vonk, M.J.S. Abb, J. Evertsson, M. Sandroni, J. Drnec, A. Stierle, E. Lundgren, H. Over, Extraordinary Stability of IrO2(110) Ultrathin Films Supported on TiO2(110) under Cathodic Polarization , J. Phys. Chem. Lett. 11 (2020) 9057-9062 (DOI: 10.1021/acs.jpclett.0c02730).
T. Weber, M.J.S. Abb, J. Evertsson, M. Sandroni, J. Drnec, V. Vonk, A. Stierle, E. Lundgren, H. Over, In situ studies of the cathodic stability of singel-crystalline IrO2(110) ultrathin films supported on RuO2(110)/Ru(0001) in an acidic environment , Phys. Chem. Chem. Phys. 22 (2020) 22956-22962 (DOI: 10.1039/D0CP03811C).
M. Behrens, G. Behrendt, Insight into Catalysts for Methanol Synthesis , ChemistryViews (2020) (DOI: 10.1002/chemv.202000066).
Q. Yang, A. Skrypnik, A. Matvienko, H. Lund, M. Holena, E. V. Kondratenko, Revealing property-performance relationships for efficient CO2 hydrogenation to higher hydrocarbons over Fe-based catalysts: Statistical analysis of literature data and its experimental validation , Applied Catalysis B: Environmental 282 (2021) 119554 (DOI: 10.1016/j.apcatb.2020.119554). Full text.
A. Arinchtein, R. Schmack, K. Kraffert, J. Radnik, P. Dietrich, R. Sachse, R. Kraehnert, Role of Water in Phase Transformations and Crystallization of Ferrihydrite and Hematite , ACS Applied Materials & Interfaces (2020) (DOI: 10.1021/acsami.0c05253).
N. Prinz, L. Schwensow, S. Wendholt, A. Jentys, M. Bauer, W. Kleist, M. Zobel, Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition , Nanoscale 12 (2020) 15800–15813 (DOI: 10.1039/D0NR01750G).
R. T. Zimmermann, J. Bremer, K. Sundmacher, Catalyst Particles for CO2 Methanation Reactors , ChemistryViews (2020) (DOI: 10.1002/chemv.202000061).
S. Weber, Seeing is Believing – Understanding Catalyst Function in 3D by Imaging , ChemistryViews (2020) (DOI: 10.1002/chemv.202000054).
T. Weber, T. Ortmann, D. Escalera‐López, M. J. S. Abb, B. Mogwitz. S. Cherevko, M. Rohnke, H. Over, Visualizing Potential‐Induced Pitting Corrosion of Ultrathin Single‐Crystalline IrO2(110) Films on RuO2(110)/Ru(0001) under Electrochemical Water Splitting Conditions , ChemCatChem 12 (2020) 855-866 (DOI: 10.1002/cctc.201901674).
K. L. Fischer, H. Freund. On the optimal design of load flexible fixed bed reactors: Integration of dynamics into the design problem. Chemical Engineering Journal 393 (2020) 124722 (DOI: 10.1016/j.cej.2020.124722).
J.-J. Velasco-Vélez, C.-H. Chuang, D. Gao, Q. Zhu, D. Ivanov, H.-S. Jeon, R. Arrigo, R. Mom, E. Stotz, H.-L. Wu, T. Jones, B. Roldan Cuenya, A. Knop-Gericke, R. Schlögl, On the activity/selectivity and phase-stability of thermally-grown copper oxides during the electrocatalytic reduction of CO2 , ACS Catalysis 10 (2020) 11510 (DOI: 10.1021/acscatal.0c03484).
S. Kunze, P. Grosse, M. T. Bernal Lopez, I. Sinev, I. Zegkinoglou, H. Mistry, J. Timoshenko, M. Y. Hu, J. Zhao, E. E. Alp, S. W. Chee, B. Roldan Cuenya, Operando NRIXS and XAFS Investigation of Segregation Phenomena in Fe-Cu and Fe-Ag Nanoparticle Catalysts during CO2 Electroreduction , Angew. Chem. Int. Ed. 59 (2020) 22667 (DOI: 10.1002/anie.202010535).
F. Franco, C. Rettenmaier, H. S. Jeon, B. Roldan Cuenya, Transition metal-based catalysts for the electrochemical CO2 reduction: from atoms and molecules to nanostructured materials , Chem. Soc. Rev. 49 (2020) 6884 (DOI: 10.1039/D0CS00835D).
J. Timoshenko, H. S. Jeon, I. Sinev, F. T. Haase, A. Herzog, B. Roldan Cuenya, Linking the evolution of catalytic properties and structural changes in copper–zinc nanocatalysts using operando EXAFS and neural-networks , Chemical Science 11 (2020) 3727 (DOI: 10.1039/d0sc00382d).
M. Loewert, M.-A. Serrer, T. Carambia, M. Stehle, A. Zimina, K. F. Kalz, H. Lichtenberg, E. Saraçi, P. Pfeifer, J.-D. Grunwaldt, Bridging the gap between industry and synchrotron: an operando study at 30 bar over 300 h during Fischer–Tropsch synthesis , Reaction Chemistry & Engineering 5 (2020) 1071-1082 (DOI: 10.1039/C9RE00493A).
R. Zimmermann, J. Bremer, K. Sundmacher, Optimal Catalyst Particle Design for Flexible Fixed-Bed CO2 Methanation Reactors , Chemical Engineering Journal 387 (2020) 123704 (DOI: 10.1016/j.cej.2019.123704).
2019
K. L. Fischer, M. R. Langer, H. Freund, Dynamic Carbon Dioxide Methanation in a Wall-Cooled Fixed Bed Reactor: Comparative Evaluation of Reactor Models , Industrial & Engineering Chemistry Research 58 (42) (2019) 19406-19420 (DOI: 10.1021/acs.iecr.9b02863).
A. Gautam, M. Sadowski, N. Prinz, H. Eickhoff, N. Minafra, M. Ghidiu, S. P. Culver, K. Albe, T. F. Fässler, M. Zobel, W. G. Zeier, Rapid crystallization and kinetic freezing of site-disorder in the lithium superionic argyrodite Li6PS5Br , Chemistry of Materials 31 (2019) 10178-10185 (DOI: 10.1021/acs.chemmater.9b03852).
K. Exner, H. Over, Beyond the Rate-Determining Step in the Oxygen Evolution Reaction over a Single-Crystalline IrO2(110) Model Electrode: Kinetic Scaling Relations , ACS Catalysis 9 (8) (2019) 6755-6765 (DOI: 10.1021/acscatal.9b01564).
T. Weber, J. Pfrommer, M. J. S. Abb, B. Herd, O. Khalid, M. Rohnke, P. H. Lakner, J. Evertsson, S. Volkov, F. Bertram, R. Znaiguia, F. Carla, V. Vonk, E. Lundgren, A. Stierle, H. Over, Potential-Induced Pitting Corrosion of a IrO2 (110)-RuO2(110)/Ru(0001) Model Electrode Under Oxygen Evolution Reaction Conditions , ACS Catalysis 9 (7) (2019) 6530-6539 (DOI: 10.1021/acscatal.9b01402).
C. Sinn, G. Pesch, J. Thöming, L. Kiewidt, Coupled conjugate heat transfer and heat production in open-cell ceramic foams investigated using CFD , International Journal of Heat and Mass Transfer 139 (2019) 600-612 (DOI: 10.1016/j.ijheatmasstransfer.2019.05.042).
S. L. J. Thomae, N. Prinz, T. Hartmann, M. Teck, S. Correll, M. Zobel, Pushing data quality for laboratory pair distribution function experiments , Review of Scientific Instruments 90 (2019) 043905 (DOI: 10.1063/1.5093714).
2017
SPP 2080
Ausschreibungstext DFG zum Schwerpunktprogramm "Katalysatoren und Reaktoren unter dynamischen Betriebsbedingungen für die Energiespeicherung und -wandlung" (SPP 2080), Direktlink .
Pressmitteilung zu Schwerpunktprogrammen der DFG 2018: Direktlink .
