Cover Articles

Selected Featured Cover Articles

Cover Feature: "Oxidative Cleavage of Vicinal Diols Catalyzed
by Monomeric Fe-Sites Inside MFI Zeolite"

Back Cover: "Bridging the gap between industry and synchrotron:
an operando study at 30 bar over 300 h during Fischer-Tropsch synthesis"

Latest Publications


  1. Unveiling the synergistic effects of pH and Sn content for tuning the catalytic performance of Ni^0/Ni_{x}Sn_{y} intermetallic compounds dispersed on Ce-Zr mixed oxides in the aqueous phase reforming of ethylene glycol
    Rosmini, C.; Pazos Urrea, M.; Tusini, E.; Indris, S.; Kovacheva, D.; Karashanova, D.; Kolev, H.; Zimina, A.; Grunwaldt, J.-D.; Rønning, M.; Dimitrov, M.; Popova, M.
    2024. Applied catalysis / B, 350, Art.Nr.: 123904. doi:10.1016/j.apcatb.2024.123904Full textFull text of the publication as PDF document
  2. Spectroscopic and theoretical investigation of Brønsted acid sites in amorphous mixed Zr-Si oxide nanoparticles
    Scotti, N.; Borsacchi, S.; Monti, S.; Zimina, A.; Evangelisti, C.; Geppi, M.; Dambruoso, P.; Barcaro, G.; Bossola, F.; Dal Santo, V.; Ravasio, N.
    2024. Journal of Alloys and Compounds, 992, Article no: 174545. doi:10.1016/j.jallcom.2024.174545Full textFull text of the publication as PDF document
  3. Rational process design for the efficient oxidation of crude HMF-solution using AuPd/C catalysts
    Neukum, D.; Saraçi, E.; Wüst, D.; Raj Lakshmi Nilayam, A.; Sharma, S.; Grunwaldt, J.-D.
    2024. Catalysis Today, 432, Article no: 114615. doi:10.1016/j.cattod.2024.114615Full textFull text of the publication as PDF document
  4. Using CoCuGa/SiO to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenation
    Smitshuysen, T. E. L.; Lützen, M.; Zimina, A.; Sheppard, T. L.; Jakobsen, H. H.; Chorkendorff, I.; Damsgaard, C. D.
    2024. Applied Catalysis A: General, 675, Art.-Nr.: 119636. doi:10.1016/j.apcata.2024.119636Full textFull text of the publication as PDF document
  5. The enhancing effect of Co on propane non-oxidative dehydrogenation over supported Co/ZrO catalysts
    Zhang, Q.; Li, Y.; Otroshchenko, T.; Kondratenko, V. A.; Wu, K.; Fedorova, E. A.; Doronkin, D. E.; Bartling, S.; Lund, H.; Jiang, G.; Kondratenko, E. V.
    2024. Journal of Catalysis, 432, Art.-Nr.: 115440. doi:10.1016/j.jcat.2024.115440
  6. Quantitative Chemical Mapping of Pt/Rh Gauze Catalysts for Ammonia Oxidation using Resonant X-ray Tomography
    Das, S.; Stuckelberger, M. E.; Pottbacker, J.; Jakobtorweihen, S.; Schroer, C. G.; Horn, R.; Sheppard, T. L.
    2024. The Journal of Physical Chemistry C, 128 (12), 5053–5063. doi:10.1021/acs.jpcc.4c00041Full textFull text of the publication as PDF document
  7. Aqueous Phase Reforming over Platinum Catalysts on Doped Carbon Supports: Exploring Platinum–Heteroatom Interactions
    Pazos Urrea, M.; Meilinger, S.; Herold, F.; Gopakumar, J.; Tusini, E.; De Giacinto, A.; Zimina, A.; Grunwaldt, J.-D.; Chen, D.; Rønning, M.
    2024. ACS Catalysis, 14 (6), 4139–4154. doi:10.1021/acscatal.3c05385Full textFull text of the publication as PDF document
  8. Surface ZnO on zirconia is highly active for high temperature methanol synthesis
    Nikolajsen, M. T.; Grivel, J.-C.; Gaur, A.; Hansen, L. P.; Baumgarten, L.; Schjødt, N. C.; Mentzel, U. V.; Grunwaldt, J.-D.; Sehested, J.; Christensen, J. M.; Høj, M.
    2024. Journal of Catalysis, 431, Art.-Nr.: 115389. doi:10.1016/j.jcat.2024.115389Full textFull text of the publication as PDF document
  9. Effect of supports on the kind of in-situ formed ZnOₓ species and its consequence for non-oxidative propane dehydrogenation
    Zhao, D.; Kondratenko, V. A.; Doronkin, D. E.; Han, S.; Grunwaldt, J.-D.; Rodemerck, U.; Linke, D.; Kondratenko, E. V.
    2024. Catalysis Today, 428, Art.-Nr.: 114444. doi:10.1016/j.cattod.2023.114444
  10. A laboratory scale fast characterizing feedback loop for optimizing technical emission control catalysts
    Delrieux, T.; Sharma, S.; Maurer, F.; Dolcet, P.; Lausch, M.; Zimina, A.; Cárdenas, C.; Lott, P.; Casapu, M.; Sheppard, T. L.; Grunwaldt, J.-D.
    2024. Reaction Chemistry & Engineering. doi:10.1039/D4RE00168KFull textFull text of the publication as PDF document
  11. Operando Spectroscopy to Understand Dynamic Structural Changes of Solid Catalysts
    Sarma, B. B.; Grunwaldt, J.-D.
    2024. CHIMIA, 78 (5), 288–296. doi:10.2533/chimia.2024.288
  12. Structural Changes of Ni and Ni–Pt Methane Steam Reforming Catalysts During Activation, Reaction, and Deactivation Under Dynamic Reaction Conditions
    Tusini, E.; Casapu, M.; Zimina, A.; Doronkin, D. E.; Störmer, H.; Barthe, L.; Belin, S.; Grunwaldt, J.-D.
    2024. ACS Catalysis, 7463–7477. doi:10.1021/acscatal.3c05847Full textFull text of the publication as PDF document
  13. In situ imaging of precipitate formation in additively manufactured al-alloys by scanning X-ray fluorescence
    Lazar, I.; Mehta, B.; Bertschová, V.; Malladi, S. B. A.; Ren, Z.; Das, S.; Hagemann, J.; Falkenberg, G.; Frisk, K.; Mikkelsen, A.; Nyborg, L.
    2024. European Journal of Materials, 4 (1). doi:10.1080/26889277.2024.2328242Full textFull text of the publication as PDF document
  14. A Critical View on the Quantification of Model Catalyst Activity
    Reich, J.; Kaiser, S.; Heiz, U.; Grunwaldt, J.-D.; Kappes, M. M.; Esch, F.; Lechner, B. A. J.
    2024. Topics in Catalysis. doi:10.1007/s11244-024-01920-0Full textFull text of the publication as PDF document
  15. Unlocking the Mysteries of Technical Catalyst Deactivation: A View from Space
    Sharma, S.; Maurer, F.; Lott, P.; Sheppard, T. L.
    2024. ChemCatChem, Art.-Nr.: e202301655. doi:10.1002/cctc.202301655
  16. Fundamental structural and electronic understanding of palladium catalysts on nitride and oxide supports
    Huang, J.; Klahn, M.; Tian, X.; Bartling, S.; Zimina, A.; Radtke, M.; Rockstroh, N.; Naliwajko, P.; Steinfeldt, N.; Peppel, T.; Grunwaldt, J.-D.; Logsdail, A. J.; Jiao, H.; Strunk, J.
    2024. Angewandte Chemie International Edition, Art.Nr.: e202400174. doi:10.1002/anie.202400174
  17. Continuous flow oxidation of HMF using supported AuPd-alloy
    Neukum, D.; Lakshmi Nilayam, A. R.; Ludwig, M. E.; Vadarlis, A. A.; Grunwaldt, J.-D.; Saraçi, E.
    2024. Catalysis Science & Technology. doi:10.1039/D3CY01722BFull textFull text of the publication as PDF document
  18. Pushing the Efficiency of the Selective and Base‐free Air‐Oxidation of HMF by Varying the Properties of Carbon‐based Supports
    Neukum, D.; Saraci, E.; Krause, B.; Nilayam, A. R. L.; Sinigalia, A.; Grunwaldt, J.-D.
    2024. ChemCatChem. doi:10.1002/cctc.202301228
  19. Comparison of Structure and Reactivity of Hydrothermally Prepared Bi‐Mo‐Co‐Fe‐O Catalysts in Selective Propylene and Isobutene Oxidation
    Klag, L.; Baumgarten, L.; Gaur, A.; Sheppard, T. L.; Grunwaldt, J.-D.
    2024. ChemCatChem, Art.-Nr.: e202301470. doi:10.1002/cctc.202301470
  20. Highly loaded bimetallic iron-cobalt catalysts for hydrogen release from ammonia
    Chen, S.; Jelic, J.; Rein, D.; Najafishirtari, S.; Schmidt, F.-P.; Girgsdies, F.; Kang, L.; Wandzilak, A.; Rabe, A.; Doronkin, D. E.; Wang, J.; Friedel Ortega, K.; DeBeer, S.; Grunwaldt, J.-D.; Schlögl, R.; Lunkenbein, T.; Studt, F.; Behrens, M.
    2024. Nature Communications, 15 (1), Art.-Nr.: 871. doi:10.1038/s41467-023-44661-6Full textFull text of the publication as PDF document
  21. Bimetallic platinum rhenium catalyst for efficient low temperature dehydrogenation of perhydro benzyltoluene
    Strauch, D.; Weiner, P.; Sarma, B. B.; Körner, A.; Herzinger, E.; Wolf, P.; Zimina, A.; Hutzler, A.; Doronkin, D. E.; Grunwaldt, J.-D.; Wasserscheid, P.; Wolf, M.
    2024. Catalysis Science & Technology. doi:10.1039/D3CY01336G
  22. DAta from PHoton and Neutron Experiments – DAPHNE4NFDI – Annual Meeting 2023
    Dolcet, P.; Grunwaldt, J.-D.; Hövelmann, S.; Amelung, L.; Schneidewind, A.
    2024. Synchrotron Radiation News, 1–3. doi:10.1080/08940886.2023.2277655Full textFull text of the publication as PDF document
  23. Exploring structure, temperature and activity correlations in the selective oxidation of lower olefins over Bi-Mo-Co-Fe-O catalysts by spatial reactor profile measurements
    Klag, L.; Weber, S.; Horn, R.; Sheppard, T. L.; Grunwaldt, J.-D.
    2024. Catalysis Science & Technology. doi:10.1039/D3CY01445BFull textFull text of the publication as PDF document
  24. Versatile spectroscopic cell for operando studies in heterogeneous catalysis using tender X‐ray spectroscopy in fluorescence mode
    Suarez Orduz, H. A.; Heck, S.-L.; Dolcet, P.; Watier, Y.; Casapu, M.; Grunwaldt, J.-D.; Glatzel, P.
    2024. Chemistry–Methods. doi:10.1002/cmtd.202300044Full textFull text of the publication as PDF document
  25. Surface States Governing the Activity and Selectivity of Pt-Based Ammonia Slip Catalysts for Selective Ammonia Oxidation
    Marchuk, V.; Sharapa, D. I.; Grunwaldt, J.-D.; Doronkin, D. E.
    2024. ACS Catalysis, 1107–1120. doi:10.1021/acscatal.3c05019
  26. Chemical bonding effects in Sc compounds studied using X-ray absorption and X-ray photoelectron spectroscopies
    Zimina, A.; Léon, A.; Steininger, R.
    2024. Physical Chemistry Chemical Physics. doi:10.1039/D3CP04108EFull textFull text of the publication as PDF document
  27. Unlocking a Dual‐Channel Pathway in CO Hydrogenation to Methanol over Single‐Site Zirconium on Amorphous Silica
    Yang, M.; Yu, J.; Zimina, A.; Sarma, B. B.; Grunwaldt, J.-D.; Zada, H.; Wang, L.; Sun, J.
    2024. Angewandte Chemie - International Edition, 63 (4), Art.Nr.: e202312292. doi:10.1002/anie.202312292
  28. TiO₂‐CeOₓ‐Pt Hollow Nanosphere Catalyst for Low‐Temperature CO Oxidation
    Liebertseder, M.; Maliakkal, C. B.; Crone, M.; Nails, G.; Casapu, M.; Grunwaldt, J.-D.; Türk, M.; Kübel, C.; Feldmann, C.
    2024. ChemCatChem, 16 (2), e202301358. doi:10.1002/cctc.202301358Full textFull text of the publication as PDF document
  29. A review on exhaust gas after-treatment of lean-burn natural gas engines – From fundamentals to application
    Lott, P.; Casapu, M.; Grunwaldt, J.-D.; Deutschmann, O.
    2024. Applied Catalysis B: Environmental, 340, Art.Nr.: 123241. doi:10.1016/j.apcatb.2023.123241Full textFull text of the publication as PDF document
  30. Investigating local coordination and electronic nature of Cu centers in the copper complexes having aspartic and glutamic acids
    Hinge, V. K.; Bairagi, M.; Yadav, N.; Joshi, S. K.; Shrivastava, B. D.; Jha, S. N.; Bhattacharya, D.; Gaur, A.
    2024. X-Ray Spectrometry, 53 (1), 60–68. doi:10.1002/xrs.3369Full textFull text of the publication as PDF document
  31. Interactions between Iron and Nickel in Fe–Ni Nanoparticles on Y Zeolite for Co-Processing of Fossil Feedstock with Lignin-Derived Isoeugenol
    Vajglová, Z.; Gauli, B.; Mäki-Arvela, P.; Kumar, N.; Eränen, K.; Wärnå, J.; Lassfolk, R.; Simakova, I. L.; Prosvirin, I. P.; Peurla, M.; Lindén, J. K. M.; Huhtinen, H.; Paturi, P.; Doronkin, D. E.; Murzin, D. Y.
    2023. ACS Applied Nano Materials, 6 (12), 10064–10077. doi:10.1021/acsanm.3c00620Full textFull text of the publication as PDF document
  32. Correction to “Tracking and Understanding Dynamics of Atoms and Clusters of Late Transition Metals with In-Situ DRIFT and XAS Spectroscopy Assisted by DFT”
    Sarma, B. B.; Jelic, J.; Neukum, D.; Doronkin, D. E.; Huang, X.; Bernart, S.; Studt, F.; Grunwaldt, J.-D.
    2023. The Journal of Physical Chemistry C, 127 (23), Art.-Nr.: 11419. doi:10.1021/acs.jpcc.3c03075
  33. Spatially-resolved investigation of CO2 methanation over Ni/γ-Al2O3 and Ni3.2Fe/γ-Al2O3 catalysts in a packed-bed reactor
    Bhimrao Shirsath, A.; Schulte, M. L.; Kreitz, B.; Tischer, S.; Grunwaldt, J.-D.; Deutschmann, O.
    2023. Chemical Engineering Journal, Art.-Nr.: 143847. doi:10.1016/j.cej.2023.143847Full textFull text of the publication as PDF document
  34. Catalytic reactor for operando spatially resolved structure–activity profiling using high-energy X-ray diffraction
    Wollak, B.; Espinoza, D.; Dippel, A.-C.; Sturm, M.; Vrljic, F.; Gutowski, O.; Nielsen, I. G.; Sheppard, T. L.; Korup, O.; Horn, R.
    2023. Journal of Synchrotron Radiation, 30 (Pt 3), 571–581. doi:10.1107/S1600577523001613Full textFull text of the publication as PDF document
  35. Co-processing of fossil feedstock with lignin-derived model compound isoeugenol over Fe-Ni/H-Y-5.1 catalysts
    Vajglová, Z.; Gauli, B.; Mäki-Arvela, P.; Simakova, I. L.; Kumar, N.; Eränen, K.; Tirri, T.; Lassfolk, R.; Peurla, M.; Doronkin, D. E.; Murzin, D. Y.
    2023. Journal of Catalysis, 421, 101–116. doi:10.1016/j.jcat.2023.03.016Full textFull text of the publication as PDF document
  36. PdCl(NO) – an iconic compound with corrugated PdCl octagons built up by PdCl(NO) moieties
    Evers, J.; Klapötke, T. M.; Beck, W.; Völkl, M. B. R.; Oehlinger, G.; Köppe, R.; Zimina, A.; Wolf, S.
    2023. Zeitschrift für anorganische und allgemeine Chemie, 649 (6-7). doi:10.1002/zaac.202200337Full textFull text of the publication as PDF document
  37. Soot Formation in Methane Pyrolysis Reactor: Modeling Soot Growth and Particle Characterization
    Shirsath, A. B.; Mokashi, M.; Lott, P.; Müller, H.; Pashminehazar, R.; Sheppard, T.; Tischer, S.; Maier, L.; Grunwaldt, J.-D.; Deutschmann, O.
    2023. The Journal of Physical Chemistry A, 127 (9), 2136–2147. doi:10.1021/acs.jpca.2c06878
  38. An Advanced Characterization Toolbox for Selective Olefin Oxidation Catalysts
    Klag, L.; Sheppard, T. L.; Grunwaldt, J.-D.
    2023. ChemCatChem, 15 (3), Art.-Nr.: e202201276. doi:10.1002/cctc.202201276Full textFull text of the publication as PDF document
  39. Core–shell catalyst pellets for effective reaction heat management
    Zimmermann, R. T.; Weber, S.; Bremer, J.; Idakiev, V.; Pashminehazar, R.; Sheppard, T. L.; Mörl, L.; Sundmacher, K.
    2023. Chemical Engineering Journal, 457, Art.-Nr.: 140921. doi:10.1016/j.cej.2022.140921Full textFull text of the publication as PDF document
  40. Role of Iron and Cobalt in 4-Component Bi–Mo–Co–Fe–O Catalysts for Selective Isobutene Oxidation Using Complementary Operando Techniques
    Klag, L.; Gaur, A.; Stehle, M.; Weber, S.; Sheppard, T. L.; Grunwaldt, J.-D.
    2023. ACS Catalysis, 13, 14241–14256. doi:10.1021/acscatal.3c03433
  41. Methyl radical chemistry in non-oxidative methane activation over metal single sites
    Huang, X.; Eggart, D.; Qin, G.; Sarma, B. B.; Gaur, A.; Yang, J.; Pan, Y.; Li, M.; Hao, J.; Yu, H.; Zimina, A.; Guo, X.; Xiao, J.; Grunwaldt, J.-D.; Pan, X.; Bao, X.
    2023. Nature Communications, 14, Article no: 5716. doi:10.1038/s41467-023-41192-yFull textFull text of the publication as PDF document
  42. Solventless hydrodeoxygenation of isoeugenol and dihydroeugenol in the batch and continuous modes over zeolite-supported FeNi catalyst
    Vajglova, Z.; Yevdokimova, O.; Medina, A.; Eränen, K.; Tirri, T.; Hemming, J.; Linden, J.; Angervo, I.; Damlin, P.; Doronkin, D. E.; Mäki-Arvela, P.; Murzin, D.
    2023. Sustainable Energy & Fuels, 7, 4486–4504. doi:10.1039/D3SE00371J
  43. XAFS study of mixed ligand benzimidazole copper complexes having distorted coordination geometry
    Hinge, V. K.; Bairagi, M.; Yadav, N.; Shrivastava, B. D.; Jha, S. N.; Bhattacharya, D.; Gaur, A.
    2023. Journal of Molecular Structure, Article no: 135909. doi:10.1016/j.molstruc.2023.135909Full textFull text of the publication as PDF document
  44. Methane Oxidation over PdO: Towards a Better Understanding of the Influence of the Support Material
    Keller, K.; Lott, P.; Tischer, S.; Casapu, M.; Grunwaldt, J.-D.; Deutschmann, O.
    2023. ChemCatChem, 15 (11), Art.-Nr.: e202300366. doi:10.1002/cctc.202300366Full textFull text of the publication as PDF document
  45. Identifying the Structure of Supported Metal Catalysts Using Vibrational Fingerprints from Ab Initio Nanoscale Models
    Salcedo, A.; Zengel, D.; Maurer, F.; Casapu, M.; Grunwaldt, J.-D.; Michel, C.; Loffreda, D.
    2023. Small. doi:10.1002/smll.202300945Full textFull text of the publication as PDF document
  46. Structure sensitivity of alumina- and zeolite-supported platinum ammonia slip catalysts
    Marchuk, V.; Huang, X.; Grunwaldt, J.-D.; Doronkin, D. E.
    2023. Catalysis Science & Technology. doi:10.1039/D2CY02095EFull textFull text of the publication as PDF document
  47. Effect of Diffusion Constraints and ZnOx Speciation on Nonoxidative Dehydrogenation of Propane and Isobutane over ZnO-Containing Catalysts
    Zhao, D.; Gao, M.; Tian, X.; Doronkin, D. E.; Han, S.; Grunwaldt, J.-D.; Rodemerck, U.; Linke, D.; Ye, M.; Jiang, G.; Jiao, H.; Kondratenko, E. V.
    2023. ACS Catalysis, 13, 3356–3369. doi:10.1021/acscatal.2c05704Full textFull text of the publication as PDF document
  48. Nanoparticle Exsolution from Nanoporous Perovskites for Highly Active and Stable Catalysts
    Rudolph, B.; Tsiotsias, A. I.; Ehrhardt, B.; Dolcet, P.; Gross, S.; Haas, S.; Charisou, N. D.; Goula, M. A.; Mascotto, S.
    2023. Advanced Science, Art.-Nr.: 2205890. doi:10.1002/advs.202205890Full textFull text of the publication as PDF document
  49. Tracking and Understanding Dynamics of Atoms and Clusters of Late Transition Metals with In-Situ DRIFT and XAS Spectroscopy Assisted by DFT
    Sarma, B. B.; Jelic, J.; Neukum, D.; Doronkin, D. E.; Huang, X.; Studt, F.; Grunwaldt, J.-D.
    2023. The Journal of Physical Chemistry C, 127 (6), 3032–3046. doi:10.1021/acs.jpcc.2c07263Full textFull text of the publication as PDF document
  50. Fluorine Aided Stabilization of Pt Single Atoms on TiO Nanosheets and Strongly Enhanced Photocatalytic H Evolution
    Wu, S.-M.; Hwang, I.; Osuagwu, B.; Will, J.; Wu, Z.; Sarma, B. B.; Pu, F.-F.; Wang, L.-Y.; Badura, Z.; Zoppellaro, G.; Spiecker, E.; Schmuki, P.
    2023. ACS Catalysis, 13, 33–41. doi:10.1021/acscatal.2c04481Full textFull text of the publication as PDF document
  51. Design of Single-Atom Catalysts and Tracking Their Fate Using Operando and Advanced X-ray Spectroscopic Tools
    Sarma, B. B.; Maurer, F.; Doronkin, D. E.; Grunwaldt, J.-D.
    2023. Chemical Reviews, 123 (1), 379–444. doi:10.1021/acs.chemrev.2c00495Full textFull text of the publication as PDF document