Pd loading threshold for an efficient noble metal use in Pd/CeO2 methane oxidation catalysts
Zengel, D.; Marchuk, V.; Kurt, M.; Maurer, F.; Salcedo, A.; Michel, C.; Loffreda, D.; Aouine, M.; Loridant, S.; Vernoux, P.; Störmer, H.; Casapu, M.; Grunwaldt, J.-D.
2024. Applied Catalysis B: Environment and Energy, 358, Art.-Nr.: 124363. doi:10.1016/j.apcatb.2024.124363 

Unveiling the synergistic effects of pH and Sn content for tuning the catalytic performance of Ni^0/Ni_{x}Sn_{y} intermetallic compounds dispersed on Ce-Zr mixed oxides in the aqueous phase reforming of ethylene glycol
Rosmini, C.; Pazos Urrea, M.; Tusini, E.; Indris, S.; Kovacheva, D.; Karashanova, D.; Kolev, H.; Zimina, A.; Grunwaldt, J.-D.; Rønning, M.; Dimitrov, M.; Popova, M.
2024. Applied catalysis / B, 350, Art.Nr.: 123904. doi:10.1016/j.apcatb.2024.123904 

Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with in situ / operando XAS and DRIFT spectroscopy
Sarma, B. B.; Neukum, D.; Doronkin, D. E.; Lakshmi Nilayam, A. R.; Baumgarten, L.; Krause, B.; Grunwaldt, J.-D.
2024. Chemical Science. doi:10.1039/D4SC02907K 

L${}_3$-edge X-ray spectroscopy of rhodium and palladium compounds
Suarez Orduz, H. A.; Bugarin, L.; Heck, S.-L.; Dolcet, P.; Casapu, M.; Grunwaldt, J.-D.; Glatzel, P.
2024. Journal of Synchrotron Radiation, 31 (4). doi:10.1107/S1600577524004673

Spectroscopic and theoretical investigation of Brønsted acid sites in amorphous mixed Zr-Si oxide nanoparticles
Scotti, N.; Borsacchi, S.; Monti, S.; Zimina, A.; Evangelisti, C.; Geppi, M.; Dambruoso, P.; Barcaro, G.; Bossola, F.; Dal Santo, V.; Ravasio, N.
2024. Journal of Alloys and Compounds, 992, Article no: 174545. doi:10.1016/j.jallcom.2024.174545 

One‐pot cascade reaction from epoxide to carboxylic acids using bifunctional Fe‐ZSM‐5
Treu, P.; Gonçalves, D.; Lakshmi Nilayam, A. R.; Grunwaldt, J.-D.; Saraçi, E.
2024. ChemCatChem, Art.-Nr.: 202400626. doi:10.1002/cctc.202400626

Rational process design for the efficient oxidation of crude HMF-solution using AuPd/C catalysts
Neukum, D.; Saraçi, E.; Wüst, D.; Raj Lakshmi Nilayam, A.; Sharma, S.; Grunwaldt, J.-D.
2024. Catalysis Today, 432, Article no: 114615. doi:10.1016/j.cattod.2024.114615 

Using CoCu${}_2$Ga/SiO${}_2$ to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenation
Smitshuysen, T. E. L.; Lützen, M.; Zimina, A.; Sheppard, T. L.; Jakobsen, H. H.; Chorkendorff, I.; Damsgaard, C. D.
2024. Applied Catalysis A: General, 675, Art.-Nr.: 119636. doi:10.1016/j.apcata.2024.119636 

The enhancing effect of Co${}^{2+}$ on propane non-oxidative dehydrogenation over supported Co/ZrO${}_2$ catalysts
Zhang, Q.; Li, Y.; Otroshchenko, T.; Kondratenko, V. A.; Wu, K.; Fedorova, E. A.; Doronkin, D. E.; Bartling, S.; Lund, H.; Jiang, G.; Kondratenko, E. V.
2024. Journal of Catalysis, 432, Art.-Nr.: 115440. doi:10.1016/j.jcat.2024.115440

Quantitative Chemical Mapping of Pt/Rh Gauze Catalysts for Ammonia Oxidation using Resonant X-ray Tomography
Das, S.; Stuckelberger, M. E.; Pottbacker, J.; Jakobtorweihen, S.; Schroer, C. G.; Horn, R.; Sheppard, T. L.
2024. The Journal of Physical Chemistry C, 128 (12), 5053–5063. doi:10.1021/acs.jpcc.4c00041 

Aqueous Phase Reforming over Platinum Catalysts on Doped Carbon Supports: Exploring Platinum–Heteroatom Interactions
Pazos Urrea, M.; Meilinger, S.; Herold, F.; Gopakumar, J.; Tusini, E.; De Giacinto, A.; Zimina, A.; Grunwaldt, J.-D.; Chen, D.; Rønning, M.
2024. ACS Catalysis, 14 (6), 4139–4154. doi:10.1021/acscatal.3c05385 

Surface ZnO${}_x$ on zirconia is highly active for high temperature methanol synthesis
Nikolajsen, M. T.; Grivel, J.-C.; Gaur, A.; Hansen, L. P.; Baumgarten, L.; Schjødt, N. C.; Mentzel, U. V.; Grunwaldt, J.-D.; Sehested, J.; Christensen, J. M.; Høj, M.
2024. Journal of Catalysis, 431, Art.-Nr.: 115389. doi:10.1016/j.jcat.2024.115389 

Effect of supports on the kind of in-situ formed ZnOₓ species and its consequence for non-oxidative propane dehydrogenation
Zhao, D.; Kondratenko, V. A.; Doronkin, D. E.; Han, S.; Grunwaldt, J.-D.; Rodemerck, U.; Linke, D.; Kondratenko, E. V.
2024. Catalysis Today, 428, Art.-Nr.: 114444. doi:10.1016/j.cattod.2023.114444

Following the Structural Changes of Iron Oxides during Reduction under Transient Conditions
Braun, L.; Spielmann, J.; Doronkin, D. E.; Kuhn, C.; Maliugin, A.; Sharapa, D. I.; Huck, I.; Bao, J.; Tischer, S.; Studt, F.; Deutschmann, O.; Kramm, U. I.; Grunwaldt, J.-D.
2024. ChemSusChem, Art.-Nr.: e202401045. doi:10.1002/cssc.202401045

X‐Ray Multibeam Ptychography at up to 20 keV: Nano‐Lithography Enhances X‐Ray Nano‐Imaging
Li, T.; Kahnt, M.; Sheppard, T. L.; Yang, R.; Falch, K. V.; Zvagelsky, R.; Villanueva-Perez, P.; Wegener, M.; Lyubomirskiy, M.
2024. Advanced Science, Art.-Nr.: 2310075. doi:10.1002/advs.202310075 

Elucidating the Role of the State of Pd in the H${}_2$-SCR of NO${}_x$ by Operando XANES and DRIFTS
Eldridge, T. J.; Borchers, M.; Lott, P.; Grunwaldt, J.-D.; Doronkin, D. E.
2024. Catalysis Science & Technology. doi:10.1039/D4CY00574K 

Elemental Distribution in Catalyst‐Coated Membranes of Proton Exchange Membrane Water Electrolysers Tracked by Synchrotron X‐Ray Fluorescence
Rex, A.; Almeida De Campos, L.; Gottschalk, T.; Ferreira Sanchez, D.; Trinke, P.; Czioska, S.; Saraçi, E.; Bensmann, B.; Grunwaldt, J.-D.; Hanke-Rauschenbach, R.; Sheppard, T. L.
2024. Advanced Energy and Sustainability Research. doi:10.1002/aesr.202400048

Highly Active Oxidation Catalysts through Confining Pd Clusters on CeO2 Nano‐Islands
Grunwaldt, J.-D.; Gashnikova, D.; Maurer, F.; Sauter, E.; Bernart, S.; Jelic, J.; Dolcet, P.; Maliakkal, C. B.; Wang, Y.; Wöll, C.; Studt, F.; Kübel, C.; Casapu, M.
2024. Angewandte Chemie International Edition, Art. e202408511. doi:10.1002/anie.202408511

A laboratory scale fast characterizing feedback loop for optimizing technical emission control catalysts
Delrieux, T.; Sharma, S.; Maurer, F.; Dolcet, P.; Lausch, M.; Zimina, A.; Cárdenas, C.; Lott, P.; Casapu, M.; Sheppard, T. L.; Grunwaldt, J.-D.
2024. Reaction Chemistry & Engineering. doi:10.1039/D4RE00168K 

Operando Spectroscopy to Understand Dynamic Structural Changes of Solid Catalysts
Sarma, B. B.; Grunwaldt, J.-D.
2024. CHIMIA, 78 (5), 288–296. doi:10.2533/chimia.2024.288

Structural Changes of Ni and Ni–Pt Methane Steam Reforming Catalysts During Activation, Reaction, and Deactivation Under Dynamic Reaction Conditions
Tusini, E.; Casapu, M.; Zimina, A.; Doronkin, D. E.; Störmer, H.; Barthe, L.; Belin, S.; Grunwaldt, J.-D.
2024. ACS Catalysis, 7463–7477. doi:10.1021/acscatal.3c05847 

In situ imaging of precipitate formation in additively manufactured al-alloys by scanning X-ray fluorescence
Lazar, I.; Mehta, B.; Bertschová, V.; Malladi, S. B. A.; Ren, Z.; Das, S.; Hagemann, J.; Falkenberg, G.; Frisk, K.; Mikkelsen, A.; Nyborg, L.
2024. European Journal of Materials, 4 (1). doi:10.1080/26889277.2024.2328242 

A Critical View on the Quantification of Model Catalyst Activity
Reich, J.; Kaiser, S.; Heiz, U.; Grunwaldt, J.-D.; Kappes, M. M.; Esch, F.; Lechner, B. A. J.
2024. Topics in Catalysis. doi:10.1007/s11244-024-01920-0 

Unlocking the Mysteries of Technical Catalyst Deactivation: A View from Space
Sharma, S.; Maurer, F.; Lott, P.; Sheppard, T. L.
2024. ChemCatChem, Art.-Nr.: e202301655. doi:10.1002/cctc.202301655

Fundamental structural and electronic understanding of palladium catalysts on nitride and oxide supports
Huang, J.; Klahn, M.; Tian, X.; Bartling, S.; Zimina, A.; Radtke, M.; Rockstroh, N.; Naliwajko, P.; Steinfeldt, N.; Peppel, T.; Grunwaldt, J.-D.; Logsdail, A. J.; Jiao, H.; Strunk, J.
2024. Angewandte Chemie International Edition, Art.Nr.: e202400174. doi:10.1002/anie.202400174

Continuous flow oxidation of HMF using supported AuPd-alloy
Neukum, D.; Lakshmi Nilayam, A. R.; Ludwig, M. E.; Vadarlis, A. A.; Grunwaldt, J.-D.; Saraçi, E.
2024. Catalysis Science & Technology. doi:10.1039/D3CY01722B 

Pushing the Efficiency of the Selective and Base‐free Air‐Oxidation of HMF by Varying the Properties of Carbon‐based Supports
Neukum, D.; Saraci, E.; Krause, B.; Nilayam, A. R. L.; Sinigalia, A.; Grunwaldt, J.-D.
2024. ChemCatChem. doi:10.1002/cctc.202301228

Comparison of Structure and Reactivity of Hydrothermally Prepared Bi‐Mo‐Co‐Fe‐O Catalysts in Selective Propylene and Isobutene Oxidation
Klag, L.; Baumgarten, L.; Gaur, A.; Sheppard, T. L.; Grunwaldt, J.-D.
2024. ChemCatChem, Art.-Nr.: e202301470. doi:10.1002/cctc.202301470

Highly loaded bimetallic iron-cobalt catalysts for hydrogen release from ammonia
Chen, S.; Jelic, J.; Rein, D.; Najafishirtari, S.; Schmidt, F.-P.; Girgsdies, F.; Kang, L.; Wandzilak, A.; Rabe, A.; Doronkin, D. E.; Wang, J.; Friedel Ortega, K.; DeBeer, S.; Grunwaldt, J.-D.; Schlögl, R.; Lunkenbein, T.; Studt, F.; Behrens, M.
2024. Nature Communications, 15 (1), Art.-Nr.: 871. doi:10.1038/s41467-023-44661-6 

Bimetallic platinum rhenium catalyst for efficient low temperature dehydrogenation of perhydro benzyltoluene
Strauch, D.; Weiner, P.; Sarma, B. B.; Körner, A.; Herzinger, E.; Wolf, P.; Zimina, A.; Hutzler, A.; Doronkin, D. E.; Grunwaldt, J.-D.; Wasserscheid, P.; Wolf, M.
2024. Catalysis Science & Technology. doi:10.1039/D3CY01336G

DAta from PHoton and Neutron Experiments – DAPHNE4NFDI – Annual Meeting 2023
Dolcet, P.; Grunwaldt, J.-D.; Hövelmann, S.; Amelung, L.; Schneidewind, A.
2024. Synchrotron Radiation News, 1–3. doi:10.1080/08940886.2023.2277655 

Exploring structure, temperature and activity correlations in the selective oxidation of lower olefins over Bi-Mo-Co-Fe-O catalysts by spatial reactor profile measurements
Klag, L.; Weber, S.; Horn, R.; Sheppard, T. L.; Grunwaldt, J.-D.
2024. Catalysis Science & Technology, 14 (4), 863–877. doi:10.1039/D3CY01445B 

Versatile spectroscopic cell for operando studies in heterogeneous catalysis using tender X‐ray spectroscopy in fluorescence mode
Suarez Orduz, H. A.; Heck, S.-L.; Dolcet, P.; Watier, Y.; Casapu, M.; Grunwaldt, J.-D.; Glatzel, P.
2024. Chemistry–Methods. doi:10.1002/cmtd.202300044 

Surface States Governing the Activity and Selectivity of Pt-Based Ammonia Slip Catalysts for Selective Ammonia Oxidation
Marchuk, V.; Sharapa, D. I.; Grunwaldt, J.-D.; Doronkin, D. E.
2024. ACS Catalysis, 1107–1120. doi:10.1021/acscatal.3c05019

Chemical bonding effects in Sc compounds studied using X-ray absorption and X-ray photoelectron spectroscopies
Zimina, A.; Léon, A.; Steininger, R.
2024. Physical Chemistry Chemical Physics. doi:10.1039/D3CP04108E 

Unlocking a Dual‐Channel Pathway in CO${}_2$ Hydrogenation to Methanol over Single‐Site Zirconium on Amorphous Silica
Yang, M.; Yu, J.; Zimina, A.; Sarma, B. B.; Grunwaldt, J.-D.; Zada, H.; Wang, L.; Sun, J.
2024. Angewandte Chemie - International Edition, 63 (4), Art.Nr.: e202312292. doi:10.1002/anie.202312292

TiO₂‐CeOₓ‐Pt Hollow Nanosphere Catalyst for Low‐Temperature CO Oxidation
Liebertseder, M.; Maliakkal, C. B.; Crone, M.; Nails, G.; Casapu, M.; Grunwaldt, J.-D.; Türk, M.; Kübel, C.; Feldmann, C.
2024. ChemCatChem, 16 (2), e202301358. doi:10.1002/cctc.202301358 

A review on exhaust gas after-treatment of lean-burn natural gas engines – From fundamentals to application
Lott, P.; Casapu, M.; Grunwaldt, J.-D.; Deutschmann, O.
2024. Applied Catalysis B: Environmental, 340, Art.Nr.: 123241. doi:10.1016/j.apcatb.2023.123241 

Investigating local coordination and electronic nature of Cu centers in the copper complexes having aspartic and glutamic acids
Hinge, V. K.; Bairagi, M.; Yadav, N.; Joshi, S. K.; Shrivastava, B. D.; Jha, S. N.; Bhattacharya, D.; Gaur, A.
2024. X-Ray Spectrometry, 53 (1), 60–68. doi:10.1002/xrs.3369 

Interactions between Iron and Nickel in Fe–Ni Nanoparticles on Y Zeolite for Co-Processing of Fossil Feedstock with Lignin-Derived Isoeugenol
Vajglová, Z.; Gauli, B.; Mäki-Arvela, P.; Kumar, N.; Eränen, K.; Wärnå, J.; Lassfolk, R.; Simakova, I. L.; Prosvirin, I. P.; Peurla, M.; Lindén, J. K. M.; Huhtinen, H.; Paturi, P.; Doronkin, D. E.; Murzin, D. Y.
2023. ACS Applied Nano Materials, 6 (12), 10064–10077. doi:10.1021/acsanm.3c00620 

Correction to “Tracking and Understanding Dynamics of Atoms and Clusters of Late Transition Metals with In-Situ DRIFT and XAS Spectroscopy Assisted by DFT”
Sarma, B. B.; Jelic, J.; Neukum, D.; Doronkin, D. E.; Huang, X.; Bernart, S.; Studt, F.; Grunwaldt, J.-D.
2023. The Journal of Physical Chemistry C, 127 (23), Art.-Nr.: 11419. doi:10.1021/acs.jpcc.3c03075

Spatially-resolved investigation of CO2 methanation over Ni/γ-Al2O3 and Ni3.2Fe/γ-Al2O3 catalysts in a packed-bed reactor
Bhimrao Shirsath, A.; Schulte, M. L.; Kreitz, B.; Tischer, S.; Grunwaldt, J.-D.; Deutschmann, O.
2023. Chemical Engineering Journal, Art.-Nr.: 143847. doi:10.1016/j.cej.2023.143847 

Catalytic reactor for operando spatially resolved structure–activity profiling using high-energy X-ray diffraction
Wollak, B.; Espinoza, D.; Dippel, A.-C.; Sturm, M.; Vrljic, F.; Gutowski, O.; Nielsen, I. G.; Sheppard, T. L.; Korup, O.; Horn, R.
2023. Journal of Synchrotron Radiation, 30 (Pt 3), 571–581. doi:10.1107/S1600577523001613 

Co-processing of fossil feedstock with lignin-derived model compound isoeugenol over Fe-Ni/H-Y-5.1 catalysts
Vajglová, Z.; Gauli, B.; Mäki-Arvela, P.; Simakova, I. L.; Kumar, N.; Eränen, K.; Tirri, T.; Lassfolk, R.; Peurla, M.; Doronkin, D. E.; Murzin, D. Y.
2023. Journal of Catalysis, 421, 101–116. doi:10.1016/j.jcat.2023.03.016 

PdCl(NO) – an iconic compound with corrugated Pd${}_4$Cl${}_4$ octagons built up by Pd${}_2$Cl${}_2$(NO)${}_2$ moieties
Evers, J.; Klapötke, T. M.; Beck, W.; Völkl, M. B. R.; Oehlinger, G.; Köppe, R.; Zimina, A.; Wolf, S.
2023. Zeitschrift für anorganische und allgemeine Chemie, 649 (6-7). doi:10.1002/zaac.202200337 

Soot Formation in Methane Pyrolysis Reactor: Modeling Soot Growth and Particle Characterization
Shirsath, A. B.; Mokashi, M.; Lott, P.; Müller, H.; Pashminehazar, R.; Sheppard, T.; Tischer, S.; Maier, L.; Grunwaldt, J.-D.; Deutschmann, O.
2023. The Journal of Physical Chemistry A, 127 (9), 2136–2147. doi:10.1021/acs.jpca.2c06878

An Advanced Characterization Toolbox for Selective Olefin Oxidation Catalysts
Klag, L.; Sheppard, T. L.; Grunwaldt, J.-D.
2023. ChemCatChem, 15 (3), Art.-Nr.: e202201276. doi:10.1002/cctc.202201276 

Core–shell catalyst pellets for effective reaction heat management
Zimmermann, R. T.; Weber, S.; Bremer, J.; Idakiev, V.; Pashminehazar, R.; Sheppard, T. L.; Mörl, L.; Sundmacher, K.
2023. Chemical Engineering Journal, 457, Art.-Nr.: 140921. doi:10.1016/j.cej.2022.140921 

Role of Iron and Cobalt in 4-Component Bi–Mo–Co–Fe–O Catalysts for Selective Isobutene Oxidation Using Complementary Operando Techniques
Klag, L.; Gaur, A.; Stehle, M.; Weber, S.; Sheppard, T. L.; Grunwaldt, J.-D.
2023. ACS Catalysis, 13, 14241–14256. doi:10.1021/acscatal.3c03433

Methyl radical chemistry in non-oxidative methane activation over metal single sites
Huang, X.; Eggart, D.; Qin, G.; Sarma, B. B.; Gaur, A.; Yang, J.; Pan, Y.; Li, M.; Hao, J.; Yu, H.; Zimina, A.; Guo, X.; Xiao, J.; Grunwaldt, J.-D.; Pan, X.; Bao, X.
2023. Nature Communications, 14, Article no: 5716. doi:10.1038/s41467-023-41192-y 

Solventless hydrodeoxygenation of isoeugenol and dihydroeugenol in the batch and continuous modes over zeolite-supported FeNi catalyst
Vajglova, Z.; Yevdokimova, O.; Medina, A.; Eränen, K.; Tirri, T.; Hemming, J.; Linden, J.; Angervo, I.; Damlin, P.; Doronkin, D. E.; Mäki-Arvela, P.; Murzin, D.
2023. Sustainable Energy & Fuels, 7, 4486–4504. doi:10.1039/D3SE00371J

XAFS study of mixed ligand benzimidazole copper complexes having distorted coordination geometry
Hinge, V. K.; Bairagi, M.; Yadav, N.; Shrivastava, B. D.; Jha, S. N.; Bhattacharya, D.; Gaur, A.
2023. Journal of Molecular Structure, Article no: 135909. doi:10.1016/j.molstruc.2023.135909 

Methane Oxidation over PdO: Towards a Better Understanding of the Influence of the Support Material
Keller, K.; Lott, P.; Tischer, S.; Casapu, M.; Grunwaldt, J.-D.; Deutschmann, O.
2023. ChemCatChem, 15 (11), Art.-Nr.: e202300366. doi:10.1002/cctc.202300366 

Identifying the Structure of Supported Metal Catalysts Using Vibrational Fingerprints from Ab Initio Nanoscale Models
Salcedo, A.; Zengel, D.; Maurer, F.; Casapu, M.; Grunwaldt, J.-D.; Michel, C.; Loffreda, D.
2023. Small. doi:10.1002/smll.202300945 

Structure sensitivity of alumina- and zeolite-supported platinum ammonia slip catalysts
Marchuk, V.; Huang, X.; Grunwaldt, J.-D.; Doronkin, D. E.
2023. Catalysis Science & Technology. doi:10.1039/D2CY02095E 

Effect of Diffusion Constraints and ZnOx Speciation on Nonoxidative Dehydrogenation of Propane and Isobutane over ZnO-Containing Catalysts
Zhao, D.; Gao, M.; Tian, X.; Doronkin, D. E.; Han, S.; Grunwaldt, J.-D.; Rodemerck, U.; Linke, D.; Ye, M.; Jiang, G.; Jiao, H.; Kondratenko, E. V.
2023. ACS Catalysis, 13, 3356–3369. doi:10.1021/acscatal.2c05704 

Nanoparticle Exsolution from Nanoporous Perovskites for Highly Active and Stable Catalysts
Rudolph, B.; Tsiotsias, A. I.; Ehrhardt, B.; Dolcet, P.; Gross, S.; Haas, S.; Charisou, N. D.; Goula, M. A.; Mascotto, S.
2023. Advanced Science, Art.-Nr.: 2205890. doi:10.1002/advs.202205890 

Tracking and Understanding Dynamics of Atoms and Clusters of Late Transition Metals with In-Situ DRIFT and XAS Spectroscopy Assisted by DFT
Sarma, B. B.; Jelic, J.; Neukum, D.; Doronkin, D. E.; Huang, X.; Studt, F.; Grunwaldt, J.-D.
2023. The Journal of Physical Chemistry C, 127 (6), 3032–3046. doi:10.1021/acs.jpcc.2c07263 

Fluorine Aided Stabilization of Pt Single Atoms on TiO${}_2$ Nanosheets and Strongly Enhanced Photocatalytic H${}_2$ Evolution
Wu, S.-M.; Hwang, I.; Osuagwu, B.; Will, J.; Wu, Z.; Sarma, B. B.; Pu, F.-F.; Wang, L.-Y.; Badura, Z.; Zoppellaro, G.; Spiecker, E.; Schmuki, P.
2023. ACS Catalysis, 13, 33–41. doi:10.1021/acscatal.2c04481 

Design of Single-Atom Catalysts and Tracking Their Fate Using Operando and Advanced X-ray Spectroscopic Tools
Sarma, B. B.; Maurer, F.; Doronkin, D. E.; Grunwaldt, J.-D.
2023. Chemical Reviews, 123 (1), 379–444. doi:10.1021/acs.chemrev.2c00495